High ring and ball softening point hot melt backsize adhesive composition

ABSTRACT

Backsize compositions, which result in tufted carpets of improved temperature resistance, comprise a blend of an ethylene/vinyl ester copolymer, a low molecular weight high density polyethylene, paraffin wax, antioxidant, filler, a dicyclopentadiene alkylation polymer, and an aliphatic thermoplastic hydrocarbon resin substantially free of polymerized aromatics.

United States Patent [191 Wright, Jr.

[4 1 Oct. 7, 1975 HIGH RING AND BALL SOFTENING POINT HOT MELT BACKSIZE ADHESIVE COMPOSITION [75] Inventor: Kenneth Yerxa Wright, Jr.,

Wilmington, Del.

[73] Assignee: E. I. Du Pont de Nemours and Company, Wilmington, Del.

22 Filed: Sept. 26, 1974 2 1 Appl. No.: 509,563

[52] US. Cl 428/97; 260/28.5 AV; 260/887 [51] Int. Cl. D03D 27/00; D041-1 11/00 [58] Field of Search 161/62-67;

117/136,138.8 A, 143 A, 161 UZ, 161 UD, l6l UH, DIG. 5; 260/28.5 D, 28.5 AV, 887, 897 R, 897 A, 897 B, 901

[56] References Cited UNITED STATES PATENTS 3,583,936 6/1971 Stahl 260/28.5 AV

' Primary Examiner-Marion E. McCamish [5 7] ABSTRACT 14 Claims, No Drawings BACKGROUND or THE INVENTION l. Field of the Invention V This invention relates to Carpet backsizing, and more particularly, it relates to high ring and ball softeniing point hot melt backsize adhesive compositions.

2. Description of the Prior Art Backsizing of tufted carpets with hot melt backsize adhesives has been known now for some years. US. Pat. No. 3,551,231 discloses a process for applying a hot melt backsize adhesive blend of ethylene/vinyl ester copolymer, petroleum wax, and a thermoplastic resin. Satisfactory carpets are made by applying a critical pressure on the tufted structure while it is in contact with the hot melt adhesive applicator roll. The necessity of maintaining such critical pressure during the adhesive application detracts from process flexibility.

US. Pat. No. 3,684,600 discloses the application of a low viscosity precoat adhesive to the backside of the tufted structure prior to the application of the hot melt backsize adhesive compositon. By using the precoat adhesive, the necessity of maintaining a critical pressure on the carpet during the hot melt adhesive application can be eliminated. The backsize adhesive composition containsethylene/vinyl ester copolymer, low molecular weight, low density polyethylene, microcrystalline wax, aliphatic thermoplastic hydrocarbon resin, dicyclopentadiene alkylation polymer, antioxidant and filler.

U.S. Pat. No. 3,583,936 discloses a hot melt backsize adhesive composition comprising an ethylene/vinyl ester or acrylate polymer, a wax of sufficiently high melting point to yield a blend softening point of at least 190F., a blend of aliphatic thermoplastic hydrocarbon resin and a dicyclopentadiene alkylation polymer, and optionally a filler.

US. Pat. No. 3,745,054 relates to high filler content hot melt backsize adhesive compositions comprising ethylene/vinyl ester copolymer, paraffin wax, microcrystalline wax, aliphatic thermoplastic hydrocarbon resin, dicyclopentadiene alkylation polymer, antioxidant and filler.

US. Pat. No. 3,723,371 deals with the improvement in the creep property of hot melt adhesive compositions comprising ethylene/vinyl ester copolymer and an aromatic hydrocarbon-aldehyde resin. The improvement is obtained by the inclusion of crystalline wax components melting at l50F.-225F.

SUMMARY OF THE INVENTION According to the present invention there is provided a composition having a ring and ball softening point of at least about 230F. comprising (A) about 4-25 weight percent ethylene/vinyl ester copolymer having a melt index of about 2 to 150, a copolymerizable ethylene content of about 72 to 82 weight percent, a copolymerizable vinyl ester content of about 18 to 28 weight percent, wherein the acid moiety of said vinyl ester contains 1 to 4 carbon atoms, (B) about 0.7-5 weight percent of an ethylene homopolymer having a molecular weight of about l,500-3,000, a density of about 0.94-0.97 g./cm. and a melting point of about 240F.-270F., (C) about -15 weight percent of a polymer resin derived from the alkylation of aromatic compounds with dicyclopentadiene and having a softening point of about 40F.-105F., (D) about 10-15 weight percent of an aliphatic thermoplastic hydrocarbon resin substantially free of polymerized aromatics prepared from diene and olefin monomers of 5 to 7 carbon atoms, and having a softening point of about 155F.-240F.. (E) about 0.5-8 weight percent of a paraffin wax, and (F) about 25-75 weight percent filler.

According to the present invention there are further provided carpets having improved temperature resistance obtained by the use of the above compositions as the backsize adhesive.

DETAILED DESCRIPTION OF THE INVENTION It has been discovered that high melting point (about 240F.-270F.)', low molecular weight (about l,500-3,000)', high density (0.94-0.97 g./cm. LMW/l-ID polyethylene results in unexpectedly high ring and ball softening point (at least about 230F.) hot melt backsize adhesive compositions when combined with ethylene/vinyl ester copolymers, a low molecular weight alkyl aromatic polymer, an antioxidant and filler. The viscosity of suitable homopolymers of ethylene is between about 25 and 5,000 centipoises at 300F. Other high melting point (240F.-455F.) and high density hydrocarbons that are similar in their general nature to polyethylene'nevertheless do not result in ring and ball softening points higher than about 210F. (cf., Table I).

The maximum desirable blend ring and ball softening point is dictated by the application temperature of the hot melt blend during carpet backsizing. Generally steam is used for heating the blend at the coater and the customarily available steam pressure is around 125 lb./in. gauge (353F. Thus the blend should have the desired operating viscosity at the blend temperature of about 300-320F. 1f the ring and ball softening point of the blend is much above 250F. the blend viscosity might be too high at the available operating temperatures. Thus a ring and ball softening point of about 230F.-'250F. affords the best compromise of high temperature resistance of the resulting carpet and desirably low operating viscosity at readily available ap plication temperatures.

As the ethylene homopolymer ingredient it is suitable to employ products that are obtained either by direct polymerization or by thermally cracking high density ethylene polymers.

The low molecular weight-high density polyethylene is present in the composition of the present invention in about 0.7-5 weight percent, preferably about 1.7-3 weight percent. The range of 2.7-2.9 percent is particularly preferred.

Ethylene copolymers most useful in the present invention are copolymers of ethylene with vinyl esters of lower carboxylic acids. Such ethylene/vinyl ester copolymers can be prepared by known techniques, such as illustrated in US. Pat. 2,200,429 and US. Pat. No. 2,703,794. While an ethylene/vinyl acetate copolymer is preferred, other ethylene copolymers, such as those of vinyl formate, vinyl propionate, and vinyl butyrate, are useful as well. The suitable ethylene copolymers have melt indexes, as measured by ASTM 123 8-52T, of about 2-150, preferably about 10-25, with polymerized ethylene content of about weight percent. Correspondingly, the polymerized ester content of useful ethylene copolymers is about 25 weight percent. Additionally, ethylene copolymers containing minor amounts (i.e., up to about 3 weight percent) of polymerizable comonomers, such as acrylic acid, methacrylic acid, itaconic acid, acrylamide, beta dimethylaminoethyl methacrylate, beta hydroxyethyl acrylate,

diallyl maleate, diallyl phthalate, diallyl ether, or ethyl- 5 quired, a precoat consisting of a low molecular weight, ene glycol dimethacrylate, are useful as well. low or high density homopolymer of ethylene, micro- The ethylene copolymer should be present in the crystalline wax, low molecular weight dicyclopenblend in about 4-25 weight percent, preferably about tadiene alkylation polymer, aliphatic thermoplastic hy- 8-25 weight percent. drocarbon resin and an antioxidant, can be applied Low molecular weight dicyclopentadiene alkylation 10 pri r o h application of the main backsize composipolymers suitable for the compositions of the present tiOn described above. The high r ing and all softeninvention have ring and ball softening points of about ing Point of the Present compositions Provides Several 40F .105F, Th are d ib d i Us P N advantages for the carpets wherein such compositions 3,023,200 wherein it is stated that the term alkylaare used as the backsize adhesive: heat steaming tion" refers to the formation of a carbon to carbon tapes can be pp more q y and with less risk of bond between an aromatic nucleus and a dicyclopeng raveling; Softening of melt due to heat Such as tadiene nucleus. Also this patent describes hos dicyclobuilding heaters, Solar heat, P during transit, pentadiene lk m i polymers can b prepared i h will be less prevalent. Placing a lower softening point desired softening points and molecular weights. Partic- Carp t, even temporarily, over a hot air outlet can ularly useful resins have pecific gravities of about cause unintentional softening, adhesive migration an 0.9-1 1, melt viscosities of about 1 poise over the temresultant delamination 0f the p resistance tQ perature range of about 175F 265F and oftening iS customarily tested first predrying the points of about 55F.-90F. The low molecular weight rp for 2 hours at 2 The lower Softening p in dicyclopentadiene alkylation polymers are present in blend carpets can delaminate under thCSC conditions. about 1() 15 i ht percent The following examples, wherein all parts and per- As a further ingredient aliphatic thermoplastic petro- Centages are y Weight, except where Otherwise p leum hydrocarbon resins, such as d ib d i C fied, further illustrate the advantages of the present indian Pat. No. 531,202, are employed. As set forth vention. therein, these resins are prepared from reactive olefins EXAMPLES 1-2 and diene monomers having low carbon atoms content Backsize adhesive blends of US. Pat. Nos. 3,55 1,231 (5-7 carbon atoms), and are substantially free of polyand 3,684,600 have ring and ball softening points of merized aromatics. Of the resins therein described, about 210F. A typical example of such a blend is as those having molecular weights of about 800l,750, follows: iodine numbers of about 40-66, and ring and ball soft- 8.1 percent ethylene/vinyl acetate copolymer n g p n (ASTM ut 155F.-240F.,. 0.9 percent paraffin wax, melting point: 149F., and especially above 215F., are preferred. These res- (Pacemaker 53, available from Cities Service Oil ins can be present in an amount of about 10-15 weight Company) percent. 1.24 low molecular weight, low density (LMW/LD) An additional ingredient of suitable backsize adhepolyethylene sive compositions is paraffin wax. Paraffin waxes hav- 40 5.4 percent microcrystalline wax, melting point ing a melting point of about 146F. to 158F., low nee- 177F. (Shellmax 400, available from Shell dle point penetration (about 6-24 at 77F.) and low oil Chemical Company) content (0.1-0.25 percent) are preferred. Microcrys- 12.13 percent unsaturated aliphatic thermoplastic, talline waxes (between about 160F. and 180F.) can hydrocarbon resin, melting point 212F., (Picalso be used. Generally, the wax is present in about copale 100SF, available from Hercules lnc. 0.5-8 weight percent. 12.13 percent dicyclopentadiene alkylation polymer, The use of an antioxidant, such as butylated hydroxymelting point 77F. (Piccovar AP 25, available toluene, in about 0.1-0.3 weight percent is advantafrom Hercules Inc. geous. 0.1 percent butylated hydroxytoluene (2,4-Di-Tert- Fillers, such as calcium carbonate, aluminum hyb t ll) drate, etc., in about 25-75 weight percent, are also in- 60.0 percent carbonate filler. corporated in the compositions of the present inven- R l t f th l m l l i ht/l w density tion. polyethylene with high melt point hydrocarbon waxes The particular manner in hich th ingr d r did not increase the ring and ball softening point: howadded to formulate the Compositions of the present inever, the use of low molecular weight/high density vention is not critical and can be accomplished by any (LMW/HD) homopolymers of ethylene resulted in a of the well known techniques. 27F. to 34F. increase in the ring and ball softening Carpets having improved temperature resistance reoint a shown in Table 1,

TABLE 1 sult when the blends of the present invention are used as the backsize adhesive composition, either with a secondary backing or alone, such as in a unitary carpet construction. If higher pill anf fuzz resistance is re- EFFECT OF HOMOPOLYMERS AND HYDROCARBONS ON RING AND BALL SOFTENING POINT Melt Point Examples ingredients F. C1 C2 C3 C4 C5 C6 C7 1 2 Eh-ax 350, Ethylene/Vinyl Acetate (opu1ymer 8.1 8.1 8.1 8.1 8.1 8.1 8.1 8.1 8.1 Paraffin wax 149 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 AC-- X 1 MW/Ll) Polycthylenc 240 1.3

TABLE 1 Continued EFFECT OF HOMOPOLYMERS AND HYDROCARBONS ON RING AND BALL SOFTENING POINT Melt Point Examples Ingredients F. C1 C2 C3 C4 C5 C6 C7 1 2 Epolene" N12 LMW/LD Polyethylcne 230 1.3 Witc0 W8689 LMW/LD Hydrocarhon 240 2.0 Witco- W8688 LMW/LD Hydrocarbon 170 2 "Acrawax" CT LMW/LD Hydrocarhon 284 L3 "Acrawax" HMS LMW/LD Hydrocarhon 455 L3 "Polywax- 1000 LMW/HD Polyethylene 235 1 3 Poly\va. 2000 LMW/HD Polyethylcne 257 1.3 X-709 LMW/HD Polyethylene 264 13 Wax and Resins" 29.7 29.7 31 31 29.7 29.7 29.7 29.7 9.7 Fillcr 60 60 58 58 60 60 60 60 60 Ring and Ball Softening Point of Blend. F. "11 164 162 182 175 208 237 244 Footnotes to Table I:

'24-2671 VAc. 17-21 m.i.. a ilable from F.. I. du Pont de Nemours and Company. "-"molecular weight: 3500. del 093. available from Allied Chemical Company. "molecular weight: 2300. density: 0.938. available from Eastman Chemical Products. ""density: 095. available from Witco Chemical Corp. "synthetie soft wax. density: 0917. available from Witco Chemical Corp. "light tan. hard solid. fatty diamide synthetic wax. density: 097. available from (ilyco Chemicals. Inc. tan. coarse powder. fatty diamide synthetic wax density: approximately 1.0. available from Glyco Chemicals. Inc. ""molecular weight; 1000. density: 0961. available from Petrolite Corp. (Bareco Div. ""moleeular weight; 2000. density: 096. available from Petrolite Corp. (Bareeo Div. ""moleeular weight: 3000. density: 0.96. experimental sample obtained from Pelrolite Corp. (Bare-1:0 Div. "mixture of 5.4% "Shellmax" 400. 12.137: Piccopale 100 SF. 12.13% Piccovar AP and 0.3); hutylated hydroxytoluene (BHT). caleium carbonate.

EXAMPLES 3-5 TABLE 111 -Continued An increase in ring and ball softening point can also be obtained by adding the LMW/HD homopolymer of l t C9 ig s 7 ethylene to the blend containing the LMW/LD homo- 5 polymer. Table 11 shows how adding a high density ho- 71. Polywax 2000 1.1 1.3 mopolymer to a blend such as C1 in Table 1 effects the Z: SF ring and ball softening point of the hot melt blend. p 13,1

7r Piccovar" AP 25 12.1 12.1 TABLE II /I Piccovar" AP 10" 12.1 7c BHT 0.2 0.2 0.2 7( N0. 9W 60.0 60.0 6010 Examples Viscosity, cps. at 31()F. 10-11 M 12 M 10-11 M C8 3 4 5 Blend ring and ball softening point. F. 210 230-237 234 Ethylene Copolymer 8.1 8.1 8.1 8.1 Paraffin Wax, F 14w. mp. 0.9 0.9 40 3311 513? 0.151 331 LOW Denslty Homo" 'low molecular weight hydrocarbon resin. rn.p. 284F.. density: 106. Color polymer" L3 L3 13 Gardner max. 10. acid no. 1. melt viscosity: 1 poise at 222C. 7 High Density H0mo- "dieyclopentadiene alkylalion polymer. m.p. 77F.. density: 0.97. melt viscosity:

polymer 0 0.7 1.1 1.7 l poise at 99C. 7! Wax and Resins 29.7 29.0 28.6 28.0 dicyclopentadiene alkylation polymer. m.p. 50F. density: 0.93. melt viscosity: 7( Filler 60 60 60 60 l poise at 85C. Bl d Ri d B 11 ""calcium carbonate filler. Softening Point. F. 212 226 234 233 (lb-Ac 8 "-'Polywax" 2000. molecular weight; 2000, density: 096. available from Pctrolite Corp. (Bareco Div.) "As given in Table l.

Alathon" 7050 (density of 0.96 g./cc.; melt index of EXAIVIPLES 6-7 The use of different resins in the increased ring and ball softening point blends of the present invention are illustrated in these Examples. The composition and properties of the blends are summarized in Table 111.

17.5 g./l0 min.) and Alathon 7840 (density 0f 0.96 g./cc.; melt index of 6.0) both high density polyethylenes were thermally cracked for about /2 minute, in the absence of oxygen, at a temperature of 550C. and 500C, respectively. Alathon 7050 yielded cracked polyethylene A and Alathon 7840 yielded cracked polyethylene B.

The cracked polyethylene products were incorporated in blends consisting of 19.8 percent Elvax" 350, 2.2 percent Pacemaker 53 wax. 45.1-48 percent Piccovar L60 (dicyclopentadiene alkylation polymer, m.p. F.), and 30 percent calcium carbonate filler, in the amounts indicated in Table IV. Blends containing LMW/HD Polywax 2000 or LMW/LD AC 8 as the polyethylene ingredient were also prepared for comparison. As shown in Table IV the use of high density cracked polyethylene resulted in a significant increase in the ring and ball softening point of the blend.

TABLE IV Blend Properties Tensile E R&B Viscosity Strength Elongation Elastic ample /1 Ethylene Homopolymer Type Point, F. cps./3l0F. lb./sq.in. 7r Modulus lb.

8 2.9 Cracked Polyethylene A" 240 8.9M 214 985 3M 9 2.9 Cracked Polyethylene B 252 13M 230 l 140 0.7M 10 1.5 Cracked Polyethylene B 236 13M 282 l 140 1.0M 1 1 2.9 Cracked Polyethylene A/B 245 124M 267 1029 l. l M 12 2.9 Cracked Polyethylene A/B 242 1 1M 333 912 1.2M C11 158 ll.7M 233 1190 (1.3M 13 1.5 Po1y\vax 2000 227 9M 270 1070 (1.9M 14 2.9 Polywax'- 2000 240 10.6M 295 994 1.6M C12 2.9 "AC"8 212 11M 261 898 4.2M

"*viscosity: 150 cps. at 280F. viscosityz 4700 cps. at 280F. ""delermined by ASTM Dl7()84.

1 claim:

1. A composition having a ring and ball softening point of at least about 230F. comprising A. about 4-25 weight percent ethylene/vinyl ester copolymer having a melt index of about 2 to 150, a copolymerizable ethylene content of about 72 to 82 weight percent. a copolymerizablc vinyl ester content of about 18 to 28 weight percent, wherein the acid moiety of said vinyl ester contains 1 to 4 carbon atoms,

B. about 0.7- weight percent of an ethylene homopolymer having a -molecular weight of about l,500-3,000, a density of about 0.94-0.97 g./cm. and a melting point of about 240F.-270F.,

C. about -15 weight percent ofa polymer resin derived from the alkylation of aromatic compounds with dicyclopentadiene and having a softening point of about 40F.-105F.,

D. about lO-l5 weight percent of an aliphatic thermoplastic hydrocarbon resin substantially free of polymerized aromatics prepared from diene and olefin monomers of 5 to 7 carbon atoms and having a softening point of about l55F.-240F.,

E. about 0.5-8 weight percent of a paraffin wax, and

F. about 25-75 weight percent filler.

2. The composition of claim 1 wherein said ethylene homopolymer is present in about 1.7-3.0 weight percent.

3. The composition of claim 2 wherein said ethylene homopolymer is present in about 2.7-2.9 weight percent.

4. The composition of claim 2 wherein said 6. The composition of claim 5 wherein said ethylene/vinyl acetate copolymer is present in about 8-25 weight percent.

7. The carpet comprised of a primary backing material stitched with closely spaced erect loops of yarn to form a tufted structure, the bottom surface of the tufted structure having as a tuft bonding backsize adhesive coating the composition of claim 5.

8. The carpet of claim 7 wherein a secondary scrim is bonded with said backsize adhesive coating to the bottom surface of the tufted structure.

9. the composition of claim 4 wherein resin (D) has a softening point of about 2l5F.-240F. and resin (C) has a softening point of about F.-90F.

10. The composition of claim 9 wherein said paraffin wax has a melting point between about l46F.-l 58F. and a needle point penetration value between about 6-24 at 77F.

11. The carpet comprised of a primary backing material stitched with closely spaced erect loops of yarn to form a tufted structure, the bottom surface of the tufted structure having as a tuft bonding backsize adhesive coating the composition of claim 10.

12. The carpet of claim 11 wherein a secondary scrim is bonded with said backsize adhesive coating to the bottom surface of the tufted structure.

13. A carpet comprised of a primary backing material stitched with closely spaced erect loops of yarn to form a tufted structure, the bottom surface of the tufted structure having as a tuft bonding backsize adhesive coating the composition of claim 1.

14. The carpet of claim 13 wherein a secondary scrim is bonded with said backsize adhesive coating to the bottom surface of the tufted structure. 

1. A COMPOSITION HAVING A RING AND BALL SOFTENING POINT OF AT LEAST ABOUT 230*F. COMPRISING A. ABOUT 4-25 WEIGHT PERCENT ETHYLENE/VINYL ESTER COPOLYMER HAVING A MELT INDEX OF ABOUT 2 TO 150, A COPOLYMERIZABLE ETHYLENE CONTENT OF ABOUT 72 TO 82 WEIGHT PERCENT, A COPOLYMERIZABLE VINYL ESTER CONTENT OF ABOUT 18 TO 28 WEIGHT PERCENT. WHEREIN THE ACID MOIETY OF SAID VINYL ESTER CONTAINS 1 TO 4 CARBON ATOMS, B. ABOUT 0.7-5 WEIGHT PERCENT OF AN ETHYLENE HOMOPOLYMER HAVING A MOLECULAR WEIGHT OF ABOUT 1,500-3,000, A DENSITY OF ABOUT 0,94-097 G./CM.3 AND MELTING POINT OF ABOUT 240*F.-270*F., C. ABOUT 10-15 WEIGHT PERCENT OF A POLYMER RESIN DERIVED FROM THE ALKYLATION OF AROMATIC COMPOUNDS WITH DICYCLOPENTADIENE AND HAVING A SOFTENING POINT OF ABOUT 40*F-105*F., D. ABOUT 10-15 WEIGHT PERCENT OF AN ALIPHATIC THERMOPLASTIC HYDROCARBON RESIN SUBSTANTIALLY FREE OF POLYMERIZED AROMATICS PREPARED FROM DIENE AND OLEFIN MONOMERS OF 5 TO 7 CARBON ATOMS AND HAVING A SOFTENING POINT OF ABOUT 155*F.-240*F., E. ABOUT 0.5-8 WEIGHT PERCENT OF A PARAFFIN WAX, AND F. ABOUT 25-75 WEIGHT PERCENT FILLER.
 2. The composition of claim 1 wherein said ethylene homopolymer is present in about 1.7-3.0 weight percent.
 3. The composition of claim 2 wherein said ethylene homopolymer is present in about 2.7-2.9 weight percent.
 4. The composition of claim 2 wherein sAid ethylene/vinyl ester copolymer has a melt index of about 10-25.
 5. The composition of claim 4 wherein said vinyl ester is vinyl acetate.
 6. The composition of claim 5 wherein said ethylene/vinyl acetate copolymer is present in about 8-25 weight percent.
 7. The carpet comprised of a primary backing material stitched with closely spaced erect loops of yarn to form a tufted structure, the bottom surface of the tufted structure having as a tuft bonding backsize adhesive coating the composition of claim
 5. 8. The carpet of claim 7 wherein a secondary scrim is bonded with said backsize adhesive coating to the bottom surface of the tufted structure.
 9. THE COMPOSITION OF CLAIM 4 WHEREIN RESIN (D) HAS A SOFTENING POINT OF ABOUT 215*F.-240*F. AND RESIN (C) HAS A SOFTENING POINT OF ABOUT 55*F.-90F.
 10. The composition of claim 9 wherein said paraffin wax has a melting point between about 146*F.-158*F. and a needle point penetration value between about 6-24 at 77*F.
 11. The carpet comprised of a primary backing material stitched with closely spaced erect loops of yarn to form a tufted structure, the bottom surface of the tufted structure having as a tuft bonding backsize adhesive coating the composition of claim
 10. 12. The carpet of claim 11 wherein a secondary scrim is bonded with said backsize adhesive coating to the bottom surface of the tufted structure.
 13. A carpet comprised of a primary backing material stitched with closely spaced erect loops of yarn to form a tufted structure, the bottom surface of the tufted structure having as a tuft bonding backsize adhesive coating the composition of claim
 14. The carpet of claim 13 wherein a secondary scrim is bonded with said backsize adhesive coating to the bottom surface of the tufted structure. 